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- CasNo112-38-9
- Purity99%
Location:Home > Pharmaceutical
Buy Quality Undecenoic acid 112-38-9 In Stock with Immediately Delivery
- Molecular Formula:C11H20O2
- Molecular Weight:184.279
- Appearance/Colour:colorless or light yellow liquid
- Vapor Pressure:0mmHg at 25°C
- Melting Point:23-25 ºC
- Refractive Index:n20/D 1.449(lit.)
- Boiling Point:300.797 ºC at 760 mmHg
- PKA:4.78±0.10(Predicted)
- Flash Point:145.815 ºC
- PSA：37.30000
- Density:0.922 g/cm3
- LogP:3.37780
Undecenoic acid(Cas 112-38-9) Usage
|
Definition |
ChEBI: An undecenoic acid having its double bond in the 10-position. It is derived from castor oil and is used for the treatment of skin problems. |
|
Preparation |
From malonic acid; by pyrolysis of ricinoleic acid or castor oil. |
|
Indications |
Undecylenic acid, like zinc undecylenate, is very effective as an external drug for treating moderate dermatophyte infections and yeast dermatitis, but it is not effective for shingles and for candida infections. Synonyms of this drug are benzevrine, micocid, undetin, and others. |
|
General Description |
10-Undecenoic acid undergoes copolymerisation with ethylene using the metallocene catalyst system Cp2ZrCl2 / methylaluminoxane. |
|
Flammability and Explosibility |
Nonflammable |
|
Synthesis |
Undecylenic acid, 10-undecylenic acid (35.4.7), is synthesized by pyrolysis at 400°C and low pressure (50 mm) an oxyderivative of oleic acid—ricinoleic acid—the glyceride of which is the main ingredient of castor oil. |
|
Purification Methods |
Purify the acid by repeated fractional crystallisation from its melt or by distillation in a vacuum. [Beilstein 2 IV 1612.] |
InChI:InChI=1/C11H20O2/c1-2-3-4-5-6-7-8-9-10-11(12)13/h2H,1,3-10H2,(H,12,13)
112-38-9 Relevant articles
A facile and selective cleavage of prenyl esters catalyzed by CeCl3·7 H2O-NaI
Yadav,Subba Reddy,Venkateshwara Rao,Chand,Prasad
, p. 137 - 139 (2002)
A highly selective cleavage of prenyl es...
Useful Direct Conversion of Tetrahydropyranyl Ethers of Fatty Alcohols into Fatty Acids
Gruiec, Regine,Noiret, Nicolas,Patin, Henri
, p. 1083 - 1085 (1995)
Tetrahydro-2-pyranyl ethers from fatty p...
Interaction of oxygen functionalized alkenes with a methylaluminoxane-zirconocene catalyst studied by NMR
Helaja, Tuulamari,Hakala, Kimmo,Helaja, Juho,Loefgren, Barbro
, p. 164 - 176 (1999)
Reactions of hydroxyl, ether and carbony...
A simple, mild and efficient procedure for selective cleavage of prenyl esters using silica-supported sodium hydrogen sulphate as a heterogenous catalyst
Ramesh,Mahender,Ravindranath,Das, Biswanath
, p. 1465 - 1467 (2003)
Prenyl esters were selectively and effic...
A New and Efficient Synthesis of Trifluoromethyl Ketones from Carboxylic Acids. Part I.
Boivin, Jean,El Kaim, Laurent,Zard, Samir Z.
, p. 2573 - 2584 (1995)
Trifluoromethyl ketones can be prepared ...
Bio-based α,ω-Functionalized Hydrocarbons from Multi-step Reaction Sequences with Bio- and Metallo-catalysts Based on the Fatty Acid Decarboxylase OleTJE
Bojarra, Samiro,Reichert, Dennis,Grote, Marius,Baraibar, álvaro Gómez,Dennig, Alexander,Nidetzky, Bernd,Mügge, Carolin,Kourist, Robert
, p. 1192 - 1201 (2018)
OleT from Jeotgalicoccus sp. ATCC 8456 c...
Oxidation of Primary Alcohols and Aldehydes to Carboxylic Acids via Hydrogen Atom Transfer
Tan, Wen-Yun,Lu, Yi,Zhao, Jing-Feng,Chen, Wen,Zhang, Hongbin
supporting information, p. 6648 - 6653 (2021/09/08)
The oxidation of primary alcohols and al...
Nitrogen-fixing of ultrasmall Pd-based bimetallic nanoclusters on carbon supports
Chen, Ping,Liang, Hai-Wei,Shen, Shan-Cheng,Wang, Lei,Xu, Shi-Long,Yin, Peng,Zhang, Le-Le
, p. 297 - 304 (2020/07/03)
Synthesis of supported Pd-based bimetall...
Synthesis from Undecylenic Acid of Macroheterocycles with Diacylhydrazine and Ester Fragments
Mingaleeva,Yakovleva,Ishmuratov, G. Yu.
, p. 895 - 898 (2019/11/03)
A three-step synthesis of potentially bi...
112-38-9 Process route
-
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6308-96-9
10,11-dibromo-undecanoic acid
-
-
2777-65-3
undec-10-ynoic acid
-
-
112-38-9
10-undecenoic acid
-
-
100399-51-7
(Z)-11-bromoundec-10-enoic acid
-
-
(10E)-11-bromoundec-10-enoic acid
-
-
C11H19BrO2
Conditions
| Conditions | Yield |
|---|---|
|
With
sodium hydride;
In
dimethyl sulfoxide;
at 25 ℃;
for 1h;
Schlenk technique;
Sealed tube;
|
40% 30% 1% 1% 2% |
-
-
6308-96-9
10,11-dibromo-undecanoic acid
-
-
2777-65-3
undec-10-ynoic acid
-
-
112-38-9
10-undecenoic acid
-
-
22202-65-9
9-undecynoic acid
-
-
undeca-9,10-dienoic acid
Conditions
| Conditions | Yield |
|---|---|
|
With
sodium amide;
In
dimethyl sulfoxide;
at 65 ℃;
for 9h;
Schlenk technique;
Sealed tube;
|
33% 13% 32% 1% |
112-38-9 Upstream products
-
2777-65-3
undec-10-ynoic acid
-
141-22-0
Ricinoleic acid
-
7493-76-7
allyl 10-undec-10-enoate
-
111-66-0
oct-1-ene
112-38-9 Downstream products
-
111-81-9
Methyl 10-undecenoate
-
94230-80-5
undec-10-enoic acid propyl ester
-
5299-57-0
ω-undecylenic acid vinyl ester
-
5455-16-3
11-Propylmercapto-undecansaeure
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