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- CasNo 589-92-4
- Purity 99%
Location:Home > Pharmaceutical
99% Purity Commercial production 4-Methylcyclohexanone 589-92-4 with Cheapest Price
- Molecular Formula: C7H12O
- Molecular Weight: 112.172
- Appearance/Colour: Clear slightly yellow liquid.
- Vapor Pressure: 1.5mmHg at 25°C
- Melting Point: -41 ºC
- Refractive Index: n20/D 1.4443(lit.)
- Boiling Point: 170 ºC at 760 mmHg
- Flash Point: 45.9 ºC
- PSA： 17.07000
- Density: 0.912 g/cm3
- LogP: 1.76560
4-Methylcyclohexanone(Cas 589-92-4) Usage
|
Preparation |
By oxidation of a mixture of cis- and trans-4-methylcyclohexanol. |
|
Synthesis Reference(s) |
The Journal of Organic Chemistry, 38, p. 2011, 1973 DOI: 10.1021/jo00951a009Tetrahedron Letters, 25, p. 173, 1984 DOI: 10.1016/S0040-4039(00)99832-0 |
|
General Description |
4-Methylcyclohexanone is a cyclic flavor ketone that is reported to be present in volatile oil of roasted sesame seeds. |
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Flammability and Explosibility |
Flammable |
|
Purification Methods |
Dry the ketone with CaSO4, then fractionally distil it. The semicarbazone has m 197o , 203.5o(dec) (from MeOH or EtOH). [White & Bishop J Am Chem Soc 62 8 1945, Vogel & Oommen J Chem Soc 774 1930, Beilstein 7 III 63, 7 IV 44.] |
InChI:InChI=1/C7H12O/c1-6-2-4-7(8)5-3-6/h6H,2-5H2,1H3
589-92-4 Relevant articles
Studies Concerning the Factors Affecting the Formation of Cyclohexanone Intermediates in the Catalytic Hydrogenation of Phenols. I. Hydrogenation of p-Cresol over Various Pd-C Catalysts
Higashijima, Michio,Nishimura, Shigeo
, p. 824 - 830 (1992)
The catalytic hydrogenation of p-cresol ...
Deciphering Reactivity and Selectivity Patterns in Aliphatic C-H Bond Oxygenation of Cyclopentane and Cyclohexane Derivatives
Martin, Teo,Galeotti, Marco,Salamone, Michela,Liu, Fengjiao,Yu, Yanmin,Duan, Meng,Houk,Bietti, Massimo
supporting information, p. 9925 - 9937 (2021/06/30)
A kinetic, product, and computational st...
(±)-Camphor sulfonic acid assisted IBX based oxidation of 1° and 2° alcohols
Kumar, Kamlesh,Joshi, Penny,Rawat, Diwan S
, (2021/09/02)
-
Synthesis method of 4-substituent cyclohexanone liquid crystal intermediate
-
Paragraph 0044; 0046-0047, (2021/05/19)
The invention discloses a synthesis meth...
Visible-light photocatalytic selective oxidation of C(sp3)-H bonds by anion-cation dual-metal-site nanoscale localized carbon nitride
Duan, Limei,Li, Peihe,Li, Wanfei,Liu, Jinghai,Liu, Ying,Liu, Zhifei,Lu, Ye,Sarina, Sarina,Wang, Jinghui,Wang, Yin,Wang, Yingying,Zhu, Huaiyong
, p. 4429 - 4438 (2021/07/12)
Selective oxidation of C(sp3)-H bonds to...
589-92-4 Process route
-
-
589-91-3
p-methylcyclohexanol
-
-
98-86-2
acetophenone
-
-
98-85-1,13323-81-4
1-Phenylethanol
-
-
589-92-4
1-methylcyclohexan-4-one
Conditions
| Conditions | Yield |
|---|---|
|
potassium hydroxide; Ru(CF3CO2)CO(PPh3)2;
at 140 ℃;
for 6h;
Equilibrium constant;
|
|
|
potassium hydroxide; Ru(CF3CO2)CO(PPh3)2;
at 140 ℃;
for 10h;
Equilibrium constant;
|
-
-
82166-21-0
methyl cyclohexane
-
-
590-67-0
1-Methylcyclohexanol
-
-
7731-29-5
trans-4-methylcyclohexan-1-ol
-
-
7731-28-4
cis-4-methylcyclohexanol
-
-
7443-52-9
(+/-)-trans-2-methylcyclohexanol
-
-
7443-70-1
cis-2-methylcyclohexanol
-
-
7443-55-2
rac-trans-3-methylcyclohexanol
-
-
5454-79-5
cis-3-methylcyclohexanol
-
-
589-92-4
1-methylcyclohexan-4-one
-
-
583-60-8
2-Methylcyclohexanone
-
-
100-49-2
cyclohexylmethyl alcohol
-
-
2043-61-0
cyclohexanecarbaldehyde
-
-
591-24-2,625-96-7
3-Methylcyclohexanone
Conditions
| Conditions | Yield |
|---|---|
|
With
C22H17BClF9N6NiO3;
at 70 ℃;
for 6h;
Inert atmosphere;
|
0.36 mmol
0.52 mmol 2.31 mmol 0.08 mmol 0.27 mmol 0.42 mmol 0.72 mmol 0.32 mmol 1.46 mmol 0.17 mmol 0.36 mmol 0.52 mmol |
|
With
[(PhSiO1.5)12(CuO)4(NaO0.5)4]; dihydrogen peroxide; nitric acid;
In
acetonitrile;
at 60 ℃;
Reagent/catalyst;
|
|
|
With
12(C6H5SiO1.5)*6Ni(2+)*6O(2-)*Na(1+)*Cl(1-)*13C4H8O2*2C7H5N*2H2O; nitric acid; 3-chloro-benzenecarboperoxoic acid;
at 60 ℃;
for 3h;
|
589-92-4 Upstream products
-
36099-51-1
3-methyl-7-oxabicyclo[4.1.0]heptane
-
589-91-3
p-methylcyclohexanol
-
7731-29-5
trans-4-methylcyclohexan-1-ol
-
7731-28-4
cis-4-methylcyclohexanol
589-92-4 Downstream products
-
5452-36-8
4-methyl-cycloheptanone
-
92860-33-8
4,4'-dimethyl-2,2'-methanediyl-bis-cyclohexanone
-
854905-11-6
(+/-)-2-((Ξ)-furfurylidene)-4-methyl-cyclohexanone
-
25672-07-5
2,6-difurfurylidene-4-methyl-cyclohexanone
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